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- W2080488081 abstract "Reaction of hydrogen sulphide with [(MeC5H4)2Mo2O2(μ-O)(μ-NPh)] (1) results in substitution of one of the terminal oxo moieties to give[(MeC5H4)2Mo2O(S)(μ-O)(μ-NPh)] (2) in high yield. The crystal structure of 2 has been determined. Whereas 1 is stable to hydrolysis in neutral media, heating 2 in wet toluene gives 1 by substitution of the terminal sulphido ligand. Addition of mineral acid to either 1 or 2 results in hydrolysis of the bridging imido moiety to give [(MeC5H4MoO(μ-O)]2 (3) or [(MeC5H4Mo2O2(μ-O)(μ-S)] (4) respectively. The former reaction has been investigated by 1H NMR spectroscopy utilising trifluoroacetic acid which shows that initial protonation of 1 occurs selectively at a terminal oxo site to give [(MeC5H4)2Mo2O(OH)(μ-O)(μ-NPh)][CF3CO2] (5). Reation of 2 with phenylisocyanate gives [(MeC5H4)2MoS(NPh)(μ-NPh)2] (6) and 1 via competitive reactions involving the replacement of oxo or sulphido moieties respectively." @default.
- W2080488081 created "2016-06-24" @default.
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- W2080488081 date "1991-03-01" @default.
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- W2080488081 title "Dimolybdenum oxo-imido complexes: reactivity of [(MeC5H4)2Mo2O2(μ-O)(μ-NPh)] and crystal structure of [(MeC5H4)2Mo2O(S)(μ-O)(μ-NPh)]" @default.
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- W2080488081 doi "https://doi.org/10.1016/0022-328x(91)86274-t" @default.
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