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- W2080488085 abstract "Abstract Tricarbonylmanganese(I) complexes of the heteroscorpionate ligand 3,3-bis(3,5-dimethylpyrazol-1-yl)propionate (bpzp) and the tris-imidazole complex fac -[Mn(CO) 3 (HIm) 3 ]Br were prepared. These and the literature-know tricarbonyl complexes based on bis(3,5-dimethylpyrazol-1-yl)acetate (bdmpza), bis(pyrazol-1-yl)acetate (bpza), 3,3-bis(3,5-dimethylpyrazol-1-yl)propionate (bdmpzp) and fac -[MnBr(CO) 3 (Hpz) 2 ] were tested for their potential to act as photoactivable CO-releasing molecules (PhotoCORMs) by the UV/Vis spectroscopy based myoglobin assay. The manganese(I) complexes of the monodentate imidazole and pyrazole ligands lack stability in solution and show fast CO release already in the dark. In the four heteroscorpionate complexes, the substitution pattern and the chain length of the carboxylate moiety have a pronounced influence on the stability in solution and the CO release properties." @default.
- W2080488085 created "2016-06-24" @default.
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- W2080488085 date "2015-05-01" @default.
- W2080488085 modified "2023-09-27" @default.
- W2080488085 title "Synthesis and characterization of heteroscorpionate-based manganese carbonyl complexes as CO-releasing molecules" @default.
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- W2080488085 doi "https://doi.org/10.1016/j.tet.2015.03.002" @default.
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