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- W2080492743 abstract "Electron-induced dissociation (EID) processes in organic and polymer films are important in a variety of applications. One scientific issue concerns the selectivity of low-energy electron bombardment to cleave a single C–H bond in hydrocarbon condensed films or adsorbed layers. We have undertaken combined TPD and FT-IRAS studies to identify and determine the purity of the surface species produced by EID of cyclohexane and benzene films on Au(1 1 1). Experimental evidence strongly supports a conclusion that EID of cyclohexane and benzene monolayer and multilayer films using incident electrons with an energy of 30 eV can be used to cleave a single C–H bond and produce a single chemisorbed product with high selectivity. An important consequence of these observations is that a variety of adsorbed hydrocarbon intermediates on Au(1 1 1) and other metal surfaces can be prepared in this manner, spectroscopically characterized, and used in studies to advance the understanding of chemical bonding, reactions and catalysis at surfaces." @default.
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- W2080492743 date "2001-10-01" @default.
- W2080492743 modified "2023-09-26" @default.
- W2080492743 title "Selectivity of bond-breaking in electron-induced dissociation of hydrocarbon films on Au surfaces" @default.
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- W2080492743 doi "https://doi.org/10.1016/s0039-6028(01)01414-5" @default.
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