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- W2080493562 abstract "DNA and RNA have been shown for the first time to function as chiral photosensitizers in aqueous solution, to effect the enantiodifferentiating photoisomerization of (Z)-cyclooctene (1Z), giving the chiral (E)-isomer in enantiomeric excesses (ee's) of up to 15%. In order to elucidate the effect of nucleotide sequence, enantiodifferentiating photoisomerization of 1Z was also performed using oligo and homopolynucleotides as chiral sensitizer. The -18.8% ee was observed by using d(T)15.d(A)15 as sensitizer, whereas sensitization by the poly(U).poly(A) duplex gave only racemic (E)-cyclooctene. From these results, oligothymidine sequence is essential for efficient enantioselective photoisomerization of 1Z." @default.
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- W2080493562 date "2000-10-01" @default.
- W2080493562 modified "2023-10-11" @default.
- W2080493562 title "Enantiodifferentiating Z-E photoisomerization of cyclooctene sensitized by DNA and RNA" @default.
- W2080493562 doi "https://doi.org/10.1093/nass/44.1.115" @default.
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