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- W2080494698 abstract "Aminepentacarbonylvanadate(1-) ion undergoes thermal substitution in the presence of π acceptor ligands to provide high yields (65–85%) of V(CO)5L−. By this method [Et4N][V(CO)5Ph2PCH2PPh2], containing an unligated PPh2, [Et4N] [V(CO)5 ((p-ClC6H4)3P)] and the first examples of the isocyanide substituted anions [V(CO)5CNR]−, where R=Me, t-Bu, cyclohexyl and phenyl have been prepared. This new method provides only monosubstituted carbonylvanadate(1-) ions and is especially important when such products are unavailable or not readily preparable by photochemical means." @default.
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- W2080494698 date "1981-07-01" @default.
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- W2080494698 title "A new route to substituted vanadium carbonyl anions. Syntheses of alkyl and aryl isocyanidepentacarbonylvanadate(1-) complexes, V(CO)5CNR−" @default.
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- W2080494698 doi "https://doi.org/10.1016/s0022-328x(81)80016-2" @default.
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