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- W2080497218 abstract "The heat capacities of Li0.5Fe2.5O4 and Li0.5Al2.5O4 were measured by adiabatic calorimetry from 5 to 545 K and no transitions or thermal anomalies were found. The lowtemperature heat capacity of Li0.5Fe2.5O4 shows the T32 dependence expected for a ferrimagnetic substance. Lattice and spin-wave contributions to the heat capacity were calculated and compared with Pollack's values. The heat capacities of both compounds above 300 K are in good agreement with values obtained by Kopp's rule based on the component oxides. At 298.15 K, the heat capacity at constant pressure Cp, the entropy So, and the function [{Go(T) − Ho(0)}T] are 34.43, 29.20, and −11.811 calth K−1 mol−1 for Li0.5Fe2.5O4; 26.79, 17.899, and −6.246 calth K−1 mol for Li0.5Al2.5O4. For the latter compound at 298.15 K ΔHfo = −(541 ± 2) kcalth mol−1 and ΔGfo = −(535 ± 2) kcalth mol−1." @default.
- W2080497218 created "2016-06-24" @default.
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- W2080497218 date "1975-07-01" @default.
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- W2080497218 title "Heat capacities and thermodynamic properties of Li0.5Fe2.5O4 and Li0.5Al2.5O4 from 5 to 545 K" @default.
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- W2080497218 doi "https://doi.org/10.1016/0021-9614(75)90010-5" @default.
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