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• W2080497673 abstract "The reaction of cis-Fe(dmpe)2H2 (1) with 13C-labeled carbon dioxide (CO2) was investigated, and trans-[Fe(dmpe)2(CO)H]·[HCO3] (5) was identified as a reaction byproduct. Both the carbonyl ligand and the bicarbonate anion are derived from CO2, and this effectively constitutes a disproportionation of CO2 to CO and CO32−. trans-[Fe(dmpe)2(CO)H].[HCO3] (5) was characterized by crystallography and by NMR spectroscopy." @default.
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• W2080497673 date "2008-06-24" @default.
• W2080497673 modified "2023-10-12" @default.
• W2080497673 title "Reductive Disproportionation of Carbon Dioxide at an Iron(II) Center" @default.
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• W2080497673 doi "https://doi.org/10.1021/om800408w" @default.
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