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• W2080515712 abstract "Sulphur dioxide photo-oxidation in sensitized SO2O2 mixtures at overall pressures of several hundred Torr was studied in the CO2 laser emission range on addition of different absorbing gases (SF6, C2H4F2, C2HCl3). The extent of conversion was correlated in each case with the absorption of energy by the specific ternary system under investigation. To explain the high reactivity found in SO2O2C2H4F2 mixtures irradiated with the 9R24 laser line, the gas temperature inside the laser beam was estimated and a model of the energy transfer processes at different irradiation frequencies was proposed. It is suggested that, complementary to the thermalized chemistry, a vibrational enhancement of SO2 oxidation can occur when the laser frequency correlates with the energy level structure of the specific molecular system employed." @default.
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• W2080515712 date "1996-01-01" @default.
• W2080515712 modified "2023-10-17" @default.
• W2080515712 title "Infrared photochemical properties of sensitized SO2O2 mixtures" @default.
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• W2080515712 doi "https://doi.org/10.1016/1010-6030(95)04194-x" @default.
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