FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080521375> ?p ?o ?g. }

• W2080521375 endingPage "883" @default.
• W2080521375 startingPage "871" @default.
• W2080521375 abstract "The effects of short range solvent structure and short range dynamical correlations are investigated for the steady state rate constant k for solution reactions influenced by diffusion. The description is in terms of a Smoluchowski equation describing relative motion of two molecules in an outer spatial translational region, supplemented by a sink term that accounts for dynamics in an inner reaction zone. In the outer region, solvent structural effects are included by a potential of mean force, which exhibits a short range well and barrier combination leading to ’’potential caging.’’ Outer region short range dynamical correlations are included via a separation-dependent diffusion coefficient, leading to ’’dynamical caging’’ as relative motion is showed at small separations. These two short range effects are neglected in standard diffusion treatments. We find that k is only modestly influenced by the above short range effects. In order to expose short range structure and correlation influence in a more sensitive way, we formulate the short range caging picture. This information focuses on events occuring at the small separations usually implied by the term ’’solvent cage.’’ At this level of description, short range effects are clearly revealed. We compare our formulation with the encounter formulation of Noyes." @default.
• W2080521375 created "2016-06-24" @default.
• W2080521375 creator A5000113075 @default.
• W2080521375 creator A5084070009 @default.
• W2080521375 date "1979-07-15" @default.
• W2080521375 modified "2023-10-16" @default.
• W2080521375 title "Short range caging effects for reactions in solution. I. Reaction rate constants and short range caging picture" @default.
• W2080521375 cites W1624281092 @default.
• W2080521375 cites W1677301091 @default.
• W2080521375 cites W1966053771 @default.
• W2080521375 cites W1969876717 @default.
• W2080521375 cites W1984041605 @default.
• W2080521375 cites W1989170204 @default.
• W2080521375 cites W1991527656 @default.
• W2080521375 cites W1991829880 @default.
• W2080521375 cites W1996238315 @default.
• W2080521375 cites W1996296772 @default.
• W2080521375 cites W1996724278 @default.
• W2080521375 cites W2000755871 @default.
• W2080521375 cites W2006961573 @default.
• W2080521375 cites W2007405930 @default.
• W2080521375 cites W2015660204 @default.
• W2080521375 cites W2025225268 @default.
• W2080521375 cites W2038140869 @default.
• W2080521375 cites W2038450717 @default.
• W2080521375 cites W2041162258 @default.
• W2080521375 cites W2046711476 @default.
• W2080521375 cites W2047723546 @default.
• W2080521375 cites W2052819394 @default.
• W2080521375 cites W2053715544 @default.
• W2080521375 cites W2060343267 @default.
• W2080521375 cites W2062446285 @default.
• W2080521375 cites W2077898467 @default.
• W2080521375 cites W2080485233 @default.
• W2080521375 cites W2081054292 @default.
• W2080521375 cites W2081152006 @default.
• W2080521375 cites W2085266415 @default.
• W2080521375 cites W2118157489 @default.
• W2080521375 cites W2151011646 @default.
• W2080521375 cites W2162488624 @default.
• W2080521375 cites W2170297409 @default.
• W2080521375 cites W2319303022 @default.
• W2080521375 cites W2405335126 @default.
• W2080521375 doi "https://doi.org/10.1063/1.438378" @default.
• W2080521375 hasPublicationYear "1979" @default.
• W2080521375 type Work @default.
• W2080521375 sameAs 2080521375 @default.
• W2080521375 citedByCount "151" @default.
• W2080521375 countsByYear W20805213752012 @default.
• W2080521375 countsByYear W20805213752013 @default.
• W2080521375 countsByYear W20805213752014 @default.
• W2080521375 countsByYear W20805213752015 @default.
• W2080521375 countsByYear W20805213752017 @default.
• W2080521375 countsByYear W20805213752019 @default.
• W2080521375 countsByYear W20805213752020 @default.
• W2080521375 countsByYear W20805213752021 @default.
• W2080521375 crossrefType "journal-article" @default.
• W2080521375 hasAuthorship W2080521375A5000113075 @default.
• W2080521375 hasAuthorship W2080521375A5084070009 @default.
• W2080521375 hasConcept C121332964 @default.
• W2080521375 hasConcept C121864883 @default.
• W2080521375 hasConcept C143002175 @default.
• W2080521375 hasConcept C148898269 @default.
• W2080521375 hasConcept C159467904 @default.
• W2080521375 hasConcept C159985019 @default.
• W2080521375 hasConcept C178790620 @default.
• W2080521375 hasConcept C185592680 @default.
• W2080521375 hasConcept C192562407 @default.
• W2080521375 hasConcept C204323151 @default.
• W2080521375 hasConcept C2780471494 @default.
• W2080521375 hasConcept C69357855 @default.
• W2080521375 hasConcept C74650414 @default.
• W2080521375 hasConcept C93391505 @default.
• W2080521375 hasConcept C97355855 @default.
• W2080521375 hasConceptScore W2080521375C121332964 @default.
• W2080521375 hasConceptScore W2080521375C121864883 @default.
• W2080521375 hasConceptScore W2080521375C143002175 @default.
• W2080521375 hasConceptScore W2080521375C148898269 @default.
• W2080521375 hasConceptScore W2080521375C159467904 @default.
• W2080521375 hasConceptScore W2080521375C159985019 @default.
• W2080521375 hasConceptScore W2080521375C178790620 @default.
• W2080521375 hasConceptScore W2080521375C185592680 @default.
• W2080521375 hasConceptScore W2080521375C192562407 @default.
• W2080521375 hasConceptScore W2080521375C204323151 @default.
• W2080521375 hasConceptScore W2080521375C2780471494 @default.
• W2080521375 hasConceptScore W2080521375C69357855 @default.
• W2080521375 hasConceptScore W2080521375C74650414 @default.
• W2080521375 hasConceptScore W2080521375C93391505 @default.
• W2080521375 hasConceptScore W2080521375C97355855 @default.
• W2080521375 hasIssue "2" @default.
• W2080521375 hasLocation W20805213751 @default.
• W2080521375 hasOpenAccess W2080521375 @default.
• W2080521375 hasPrimaryLocation W20805213751 @default.
• W2080521375 hasRelatedWork W2007194935 @default.
• W2080521375 hasRelatedWork W2031619525 @default.
• W2080521375 hasRelatedWork W2034936528 @default.
• W2080521375 hasRelatedWork W2038277038 @default.
• W2080521375 hasRelatedWork W2039077224 @default.

• next