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- W2080521778 abstract "The vinylidene complex trans-[RhCl(CCHCCCPh2OSiMe3)(PiPr3)2] (5), prepared from [RhCl(PiPr3)2]2 (1) and HCCCCCPh2OSiMe3 (2), is in equilibrium with the pentatetraenediyl isomer trans-[RhCl(CCCCHCPh2OSiMe3)(PiPr3)2] (6) in benzene solution. The reaction of the diynyl(hydrido) compound [RhH(Cl)(CCCCCPh2OSiMe3)(PiPr3)2(py)] (7) with triflic acid in THF/water afforded the functionalized rhodium(I) vinylidene trans-[RhCl(CCHC(O)CHCPh2)(PiPr3)2] (9), which was also obtained from the metallacumulene trans-[RhCl(CCCCCPh2)(PiPr3)2] (8) under analogous conditions." @default.
- W2080521778 created "2016-06-24" @default.
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- W2080521778 date "2011-01-01" @default.
- W2080521778 modified "2023-09-25" @default.
- W2080521778 title "Vinylidene and pentatetraenediyl rhodium complexes obtained from a bulky rhodium(i) dimer and a functionalized 1,3-diyne" @default.
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- W2080521778 doi "https://doi.org/10.1039/c1nj20392d" @default.
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