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- W2080541511 abstract "Single crystals of W- and Mo-doped ReSe2 have been grown by chemical vapor transport (CVT) process with bromine as a transporting agent. The nominal doping concentration for tungsten is 0.5% while EDX measurement indicates a 4% doping concentration for molybdenum. Single crystalline platelets up to 5mm×5 mm surface area and 100 μm in thickness were obtained. From the X-ray diffraction patterns, the doped crystals are found to crystallize in the triclinic-layered structure. The doping effects of the materials are characterized by temperature-dependent conductivity, optical absorption and piezoreflectance measurements. The activation energies for the impurity carriers decrease with doping. The indirect energy gaps of the doped samples show different red shifts for W- and Mo-doped samples. The direct band edge excitonic transition energies remain unchanged for W-doped samples, while for Mo-doped ReSe2 the transition energies shift toward lower energy locations. The broadening parameters of the excitonic transition features show small increase for W-doped ReSe2 due to impurity scattering, whereas for Mo-doped samples the transition features broadened significantly. The influence of the varying concentrations of the two dopants will be compared and discussed." @default.
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- W2080541511 date "2004-11-01" @default.
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- W2080541511 title "Growth and characterization of tungsten and molybdenum-doped ReSe2 single crystals" @default.
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- W2080541511 doi "https://doi.org/10.1016/j.jallcom.2004.04.009" @default.
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