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- W2080548965 abstract "Equilibrium total pressures over the named solid systems were obtained in a static system. Simultaneous establishment of equilibrium (4) by platinum black catalyst mixed with the solids allows the data to be represented in terms of the equilibria (1), (2), and (3). Bi2(SO4)3=β-Bi2O(SO4)2+SO3, (1) ΔH°=38.39, ΔS°=43.9, Tm=785, Bi2(SO4)3=α-Bi2O(SO4)2+SO3, (2) ΔH°=33.71, ΔS°=38.1, Tm=760, β-Bi2O(SO4)2=Bi2O2SO4+SO3, (3) ΔH°=41.93, ΔS°=37.3, Tm=950, SO3=SO2+1/2 O2. (4) The enthalpy (kcal mol−1) and entropy changes (cal K−1 mol−1) are assigned to the middle of the range of temperatures covered Tm (K). The unusually sluggish transformation between the low temperature α and a new high temperature β form of Bi2O(SO4)2 allowed equilibrium pressures for equilibrium (1) to be determined below the transformation temperature Tt, where the β form is metastable, as well as above Tt. Pressure data for equilibria (1) and (2) gave Tt=811±2 K. Annealing-x-ray diffraction methods gave Tt=808±3 K. The entropy change for the transformation is rather large (5.76±0.13 cal K−1 mol−1). The possible nature of the transformation is considered." @default.
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- W2080548965 date "1984-04-01" @default.
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- W2080548965 title "Equilibrium pressures over the systems bismuth trisulfate-dibismuthmonoxydisulfate and dibismuthmonoxydisulfate-dibismuthdioxymonosulfate. Slow transformation between two crystalline forms of dibismuthmonoxydisulfate" @default.
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- W2080548965 doi "https://doi.org/10.1063/1.447096" @default.
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