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- W2080552322 abstract "Abstract The gas chromatographic (GC) method for thermodynamic measurements of polymer‐solvent systems at finite concentration has been improved to extend its operating range from atmospheric pressure to over 70 atm and over 240°C. This paper describes the design and opertion of the equipment and the mathematical treatment of the GC data, and presents experimental results for n ‐hexane and isooctane in high density polyethylene. These results include the solubility isotherms, activity coefficients, and polymer‐solvent interaction parameters. The activity coefficients covering a range from 4 to 70 atm for n ‐hexane in the polymer solution were correlated successfully as a function of composition using a two‐parameter segment interaction equation." @default.
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- W2080552322 date "1973-11-01" @default.
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- W2080552322 title "Gas chromatographic determination of thermodynamic properties of polymer solutions at high pressure" @default.
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- W2080552322 doi "https://doi.org/10.1002/aic.690190609" @default.
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