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- W2080555036 abstract "We report calculated rotational transition probabilities for oriented NO(X 2Π) molecules in the J = M = Ω = 12 groundrotational state scattered from Ag(111). A comparison is made with recent experiments by Kuipers et al. on NO molecules state-selected and oriented in a Stark field. Our calculations include the two adiabatic potential energy surfaces of V+ and V− symmetry, required in a description of the dependence of the transition probabilities on the spin-orbit and Λ-doublet states. Compared with unoriented molecules, the mean rotational energy of the scattered molecules is increased (decreased) by approximately 30% when the O-end (N-end) of the molecule is directed toward the surface, in qualitative agreement with experiment." @default.
- W2080555036 created "2016-06-24" @default.
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- W2080555036 date "1989-08-01" @default.
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- W2080555036 title "Steric effects in gas-surface scattering: A quantum close-coupled study of collisions of oriented NO(X 2Π) with a Ag(111) surface" @default.
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- W2080555036 doi "https://doi.org/10.1016/0009-2614(89)87604-3" @default.
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