FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080557106> ?p ?o ?g. }

• W2080557106 endingPage "837" @default.
• W2080557106 startingPage "829" @default.
• W2080557106 abstract "A new pH oscillator has been discovered involving the system of NaClO2, Na2SO3, and H2SO4 in a continuous-flow stirred tank reactor (CSTR). While ClO2- serves as an oxidant in numerous systems exhibiting nonlinear dynamical behavior, this is the first reported chlorite-based pH oscillator. Large-amplitude oscillations in pH and potential of a platinum electrode were observed over a rather narrow concentration range. Complex dynamical behavior also was observed, including aperiodic oscillations, bistability between steady states, bistability between steady state and oscillatory state, bursting, a possible third steady state, and damped oscillations in batch. Autocatalytic oxidation of HSO3- by ClO2- is a major source of positive feedback in H+. A fast Cl+-transfer reaction between HOCl and SO32- is an important source of negative feedback. Oscillations were also obtained in the presence of Na2CO3, with the dehydration reaction of H2CO3 providing additional negative feedback. Models are proposed to account for observed behavior using computer simulations. Comparisons are made to the ClO2-−I- and ClO2−I- oscillating systems, as well as to the general model for chlorite-based chemical oscillators proposed by Rabai and Orban. A possible mechanism for chemical coupling is proposed." @default.
• W2080557106 created "2016-06-24" @default.
• W2080557106 creator A5020225128 @default.
• W2080557106 creator A5026630738 @default.
• W2080557106 creator A5038818473 @default.
• W2080557106 creator A5062461969 @default.
• W2080557106 date "2001-01-12" @default.
• W2080557106 modified "2023-10-11" @default.
• W2080557106 title "A New pH Oscillator: The Chlorite−Sulfite−Sulfuric Acid System in a CSTR" @default.
• W2080557106 cites W1963911054 @default.
• W2080557106 cites W1967921248 @default.
• W2080557106 cites W1973172262 @default.
• W2080557106 cites W1974994013 @default.
• W2080557106 cites W1981753784 @default.
• W2080557106 cites W1982095346 @default.
• W2080557106 cites W1982733756 @default.
• W2080557106 cites W1987355948 @default.
• W2080557106 cites W1997676473 @default.
• W2080557106 cites W2002610056 @default.
• W2080557106 cites W2012240681 @default.
• W2080557106 cites W2013493480 @default.
• W2080557106 cites W2026105977 @default.
• W2080557106 cites W2027019526 @default.
• W2080557106 cites W2031081865 @default.
• W2080557106 cites W2035430969 @default.
• W2080557106 cites W2047066371 @default.
• W2080557106 cites W2049281071 @default.
• W2080557106 cites W2060514809 @default.
• W2080557106 cites W2061864231 @default.
• W2080557106 cites W2066771001 @default.
• W2080557106 cites W2071967483 @default.
• W2080557106 cites W2080995933 @default.
• W2080557106 cites W2081740570 @default.
• W2080557106 cites W2090278421 @default.
• W2080557106 cites W2108724861 @default.
• W2080557106 cites W2122297879 @default.
• W2080557106 cites W2185162548 @default.
• W2080557106 cites W2319809012 @default.
• W2080557106 cites W2346675510 @default.
• W2080557106 cites W2949279080 @default.
• W2080557106 cites W2991817100 @default.
• W2080557106 doi "https://doi.org/10.1021/jp003363u" @default.
• W2080557106 hasPublicationYear "2001" @default.
• W2080557106 type Work @default.
• W2080557106 sameAs 2080557106 @default.
• W2080557106 citedByCount "29" @default.
• W2080557106 countsByYear W20805571062012 @default.
• W2080557106 countsByYear W20805571062013 @default.
• W2080557106 countsByYear W20805571062015 @default.
• W2080557106 countsByYear W20805571062016 @default.
• W2080557106 countsByYear W20805571062017 @default.
• W2080557106 countsByYear W20805571062018 @default.
• W2080557106 countsByYear W20805571062019 @default.
• W2080557106 countsByYear W20805571062022 @default.
• W2080557106 countsByYear W20805571062023 @default.
• W2080557106 crossrefType "journal-article" @default.
• W2080557106 hasAuthorship W2080557106A5020225128 @default.
• W2080557106 hasAuthorship W2080557106A5026630738 @default.
• W2080557106 hasAuthorship W2080557106A5038818473 @default.
• W2080557106 hasAuthorship W2080557106A5062461969 @default.
• W2080557106 hasConcept C121332964 @default.
• W2080557106 hasConcept C147789679 @default.
• W2080557106 hasConcept C151730666 @default.
• W2080557106 hasConcept C159467904 @default.
• W2080557106 hasConcept C161790260 @default.
• W2080557106 hasConcept C178790620 @default.
• W2080557106 hasConcept C179104552 @default.
• W2080557106 hasConcept C185592680 @default.
• W2080557106 hasConcept C189935429 @default.
• W2080557106 hasConcept C2777844515 @default.
• W2080557106 hasConcept C2779830873 @default.
• W2080557106 hasConcept C2779870107 @default.
• W2080557106 hasConcept C37263863 @default.
• W2080557106 hasConcept C62520636 @default.
• W2080557106 hasConcept C67334161 @default.
• W2080557106 hasConcept C86803240 @default.
• W2080557106 hasConcept C97292510 @default.
• W2080557106 hasConceptScore W2080557106C121332964 @default.
• W2080557106 hasConceptScore W2080557106C147789679 @default.
• W2080557106 hasConceptScore W2080557106C151730666 @default.
• W2080557106 hasConceptScore W2080557106C159467904 @default.
• W2080557106 hasConceptScore W2080557106C161790260 @default.
• W2080557106 hasConceptScore W2080557106C178790620 @default.
• W2080557106 hasConceptScore W2080557106C179104552 @default.
• W2080557106 hasConceptScore W2080557106C185592680 @default.
• W2080557106 hasConceptScore W2080557106C189935429 @default.
• W2080557106 hasConceptScore W2080557106C2777844515 @default.
• W2080557106 hasConceptScore W2080557106C2779830873 @default.
• W2080557106 hasConceptScore W2080557106C2779870107 @default.
• W2080557106 hasConceptScore W2080557106C37263863 @default.
• W2080557106 hasConceptScore W2080557106C62520636 @default.
• W2080557106 hasConceptScore W2080557106C67334161 @default.
• W2080557106 hasConceptScore W2080557106C86803240 @default.
• W2080557106 hasConceptScore W2080557106C97292510 @default.
• W2080557106 hasIssue "5" @default.
• W2080557106 hasLocation W20805571061 @default.
• W2080557106 hasOpenAccess W2080557106 @default.
• W2080557106 hasPrimaryLocation W20805571061 @default.

• next