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• W2080558273 abstract "In this report, we apply the concept of delocalization of electrons in a chain structure to an all-metal system using experimental (photoelectron spectroscopy, velocity map imaging) and first principles theoretical investigations. We show that In2Bi− is a triatomic cluster anion with a bent structure, where bismuth is the bridging atom between the two indium atoms. It is found that 6p-electrons (2π and 4σ) are delocalized over the cluster. The In–Bi bond lengths in In2Bi− are identical to bond lengths of In3Bi, which is an all-metal aromatic system analogue to Al3Bi, and are shorter than the rest of InxBi(−) clusters, showing the presence of a higher bond order." @default.
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• W2080558273 date "2009-10-01" @default.
• W2080558273 modified "2023-09-23" @default.
• W2080558273 title "Electron delocalization in a non-cyclic all-metal III–V cluster" @default.
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• W2080558273 doi "https://doi.org/10.1016/j.cplett.2009.09.046" @default.
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