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• W2080563989 abstract "Abstract A single Br/Mg exchange of 1,2‐dibromocyclopentene with i PrMgCl⋅ LiCl provides the corresponding β‐bromocyclopentenylmagnesium reagent, which can then be reacted with various electrophiles (yields: 65–82 %). In the presence of a secondary alkylmagnesium halide and Li 2 CuCl 4 (2 mol %), these 2‐bromoalkenylmagnesium compounds undergo bromine substitution and can then further react with electrophiles to give 1,2‐difunctionalised cyclopentenes (63–79 %). The mechanism of this process is discussed." @default.
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• W2080563989 date "2008-02-28" @default.
• W2080563989 modified "2023-10-18" @default.
• W2080563989 title "Selective Mono- and 1,2-Difunctionalisation of Cyclopentene Derivatives via Mg and Cu Intermediates" @default.
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• W2080563989 doi "https://doi.org/10.1002/chem.200701431" @default.
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