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- W2080571918 abstract "A series of copper manganese oxide catalysts of approximate composition Cu1+xMn2−xO4 (x = 0.54 ± 0.04), which was aged at various times and at different pH values, has been studied by X-ray photoelectron spectroscopy (XPS). In all cases, copper (II) and manganese (IV) are the only oxidation states. The copper/manganese concentration ratio exceeds the bulk value (0.5) at short ageing times, but falls to <0.4 on prolonged ageing. Sodium, which is believed to be a poison for the CO oxidation reaction; for which, the copper manganese oxide catalyst is the most useful, is formed on all samples, however, its concentration decreases significantly with increased ageing time." @default.
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- W2080571918 date "2005-01-01" @default.
- W2080571918 modified "2023-10-18" @default.
- W2080571918 title "The X-ray photoelectron spectroscopy of surface composition of aged mixed copper manganese oxide catalysts" @default.
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- W2080571918 doi "https://doi.org/10.1016/j.apsusc.2004.05.274" @default.
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