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- W2080571946 abstract "Precipitation of Al3+ at pH = 10 in excess Li2CO3 leads to an anion exchanging compound, [Al2Li(OH)6]+2CO2−3. This compound exhibits, compared to [Mg3Al(OH)8]+2CO2−3, a higher degree of size selectivity in anion exchange. The structure of the [Al2Li(OH)6]+ layers is gibbsite-like, with a (110) diffraction feature at d = 4.35 Å indicating a pronounced Al3+ ordering. As claimed originally by Serna et al., the structure is [Al2Li(OH)6]+Az−1z rather than [Al2(OH)6]Li+Az−1z, with the Li+ coordinated in the octahedral positions left vacant by Al3+. This emerges from the details of a lithium-leaching process, which proposedly leads to a novel compound, [Al2H(OH)6]+Az−1z." @default.
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- W2080571946 date "1985-12-01" @default.
- W2080571946 modified "2023-09-27" @default.
- W2080571946 title "Anion intercalation and exchange in Al(OH)3-derived compounds" @default.
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- W2080571946 doi "https://doi.org/10.1016/0022-4596(85)90278-6" @default.
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