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- W2080573693 abstract "In order to elucidate the relationship between the dielectric main-chain relaxation and molecular structure in rubbery polymers, we studied polyisobutylene, which is free from complicating factors such as stereoregularity, branching, isomerism, and crystallinity. On the basis of the known conformation in the crystal and conformations deduced in solution and in the glassy state, we assumed several probable conformations in the rubbery state, and estimated the motional units in terms of the modified Adam—Gibbs theory. A computer simulation based on the above results leads to the conclusion that the local conformation in the rubbery state retains a regularity similar to that in the crystal." @default.
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- W2080573693 date "1974-07-01" @default.
- W2080573693 modified "2023-09-23" @default.
- W2080573693 title "Relationship between dielectric behavior and molecular conformation of polyisobutylene in the rubbery state" @default.
- W2080573693 doi "https://doi.org/10.1002/pol.1974.180120704" @default.
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