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- W2080579366 abstract "Electrophilic P2Pt2+ complexes are shown to catalyze the regio- and diastereoselective oxidative cascade cyclization of poly-enes. The reactions are stereospecific with respect to the initiating alkenes geometry and suggest an all-chair, semiconcerted transition structure. Catalyst turnover after cyclization apparently occurs via β-hydride elimination and subsequent hydride abstraction (from P2Pt−H+) by added Trityl cation (in the form of trityl methyl ether or a resin version thereof) to regenerate the active P2Pt2+ state. One intriguing possibility is that the high regioselectivity observed in the β-H elimination is due to a regio-defining β-agostic resting state." @default.
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- W2080579366 date "2007-09-13" @default.
- W2080579366 modified "2023-09-23" @default.
- W2080579366 title "Regioselective Oxidative Cation-Olefin Cyclization of Poly-enes: Catalyst Turnover via Hydride Abstraction" @default.
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- W2080579366 doi "https://doi.org/10.1021/ja073573l" @default.
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