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- W2080586305 abstract "The ordinary Hückel molecular orbital (H.m.o.) method and the linear combination of molecular orbitals (l.c.m.o.) method in a perturbational form have been used to calculate the π-electron energy levels appropriate to a series of 24 Schiff bases (S.b.'s) of the type ArCH=NAr′, where Ar— and Ar—′ are unsubstituted aryl groups. The energy levels calculated by both the H.m.o. and l.c.m.o. treatments are shown to give a satisfactory account of the polarographic data for the S.b.'s reported in Part I of the present series. However, the l.c.m.o. method appears to offer a deeper insight into the variation of the half-wave potentials for the first electron transfer with the structure of the S.b." @default.
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- W2080586305 date "1968-09-15" @default.
- W2080586305 modified "2023-10-17" @default.
- W2080586305 title "Polarographic reduction of some Schiff bases in dimethylformamide. Part II. Some further theoretical considerations" @default.
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- W2080586305 doi "https://doi.org/10.1139/v68-481" @default.
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