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- W2080589405 abstract "Electronic excitation ( 6 A 1g → 4 T 1g ) energies in MnF 2 with Mg or Ca impurity are studied. The inverse of the force constant matrix (static limit of Green's function) is calculated accurately by the double exponential formula, and the distortions of the lattice around the impurity are obtained from the condition for the lattice to be stable in the harmonic approximation. They are rendered into the normal coordinates of the [MnF 6 ] 4- complexes containing the Mn 2+ ion first, second or third nearest to the impurity, and the variations of their excitation energies due to the distortion of the A 1g , E gθ and T 2gζ mode are calculated. Effects of these three modes are obtained from the comparison between the observed variation of the excitation energies and the lattice distortion under uniaxial stress, which is calculated from the condition of the minimum potential energy per unit cell." @default.
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- W2080589405 date "1983-08-01" @default.
- W2080589405 modified "2023-10-01" @default.
- W2080589405 title "Origins of Impurity-Perturbed Fluorescent Lines of MnF2" @default.
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- W2080589405 doi "https://doi.org/10.1143/jpsj.52.2936" @default.
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