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- W2080598345 abstract "Distributionsof antioxidants and u.v. absorbers in partly and fully crystallized spherulitic polypropylene were observed by u.v. and fluorescent microscopy and by scanning electron microscopy. These additives are partly pushed ahead of the growing spherulites, and the observed distribution in quenched samples has been fitted using a computer model based on exclusion of the additives from the crystallites. Diffusion coefficients for antioxidants in polypropylene melt have been obtained in this way. In fully crystallized samples there is seen to be an impurity-rich region at the spherulite boundary and a depleted zone at the centre. This is not simply due to additive rejection but also reflects a crystallinity variation within the spherulite probably due to non-crystallizable polymeric impurities." @default.
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- W2080598345 date "1978-06-01" @default.
- W2080598345 modified "2023-10-16" @default.
- W2080598345 title "Redistribution of impurities in crystallizing polymers" @default.
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- W2080598345 doi "https://doi.org/10.1016/0032-3861(78)90112-x" @default.
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