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• W2080598517 endingPage "162" @default.
• W2080598517 startingPage "148" @default.
• W2080598517 abstract "Two new dicopper(II) complexes bridged by N,N'-bis(dipropylenetriamine)oxamide (H2oxdipn), namely, [Cu2(oxdipn)](pic)2(1) and [Cu2(oxdipn)(ClO4)2] (2), where pic represents picrate ion, have been synthesized and characterized by elemental analyses, molar conductance measurements, IR and electronic spectral studies, and X-ray single crystal diffraction. In both dicopper(II) complexes, the two copper(II) ions are bridged by trans-oxdipn ligand with the Cu⋯Cu separations of 5.2536(15) and 5.231(2)Å, respectively. The copper(II) ion in complex 1 has a square-planar coordination geometry, while that in 2, a square-pyramidal. Linked with classical hydrogen bonds, the molecules of complex 1 consist of a one-dimensional chain, while complex 2 molecules result in a two-dimensional structure. Numerous hydrogen bonds link complex 1 or 2 into a 2-D infinite network. In vitro cytotoxicity experiment shows that the two dicopper(II) complexes exhibit cytotoxic effects against the selected tumor cell lines. The reactivity towards herring sperm DNA (HS-DNA) and bovine serum albumin (BSA) reveals that the two dicopper(II) complexes can interact with the DNA in the mode of intercalation, and effectively quench the intrinsic fluorescence of BSA via a static mechanism. The influence of different counterions in this kind of dicopper(II) complexes on DNA/BSA-binding properties, and the in vitro cytotoxic activities was investigated." @default.
• W2080598517 created "2016-06-24" @default.
• W2080598517 creator A5019149465 @default.
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• W2080598517 date "2015-02-01" @default.
• W2080598517 modified "2023-10-15" @default.
• W2080598517 title "Synthesis and crystal structure of new dicopper(II) complexes with N,N′-bis-(dipropylenetriamine)oxamide as bridging ligand: Effects of the counterions on DNA/protein-binding property and in vitro antitumor activity" @default.
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• W2080598517 doi "https://doi.org/10.1016/j.jphotobiol.2014.12.030" @default.
• W2080598517 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/25635907" @default.
• W2080598517 hasPublicationYear "2015" @default.
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