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- W2080598814 abstract "The structure of methyl silatrane is investigated by gas-phase electron diffraction at 185° C. The molecule possesses C3v symmetry. The result obtained for the Si—N distance (2.45(5) Å) indicates essentially no dative bonding between Si and N in the gas phase. This result is quite different from the solid-state result which indicates a Si←N dative bond length of 2.175(4) Å. Other structural parameters compare favorably with both the solid state results and with values obtained in the gas phase for similar molecules." @default.
- W2080598814 created "2016-06-24" @default.
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- W2080598814 date "1980-05-01" @default.
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- W2080598814 title "The structure of methyl silatrane (1-methyl-2,8,9-trioxa-5-aza-1-silabicyclo(3.3.3)undecane) as determined by gas phase electron diffraction" @default.
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- W2080598814 doi "https://doi.org/10.1016/0022-2860(80)80136-0" @default.
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