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• W2080608344 abstract "This work reports experimental data and kinetic modeling of solvent-free glycerolysis of olive oil using a commercial immobilized lipase (Novozym 435) in the presence of Triton X-100 surfactant for the production of monoacylglycerols (MAG) and diacylglycerols (DAG). The experiments were performed in batch mode evaluating the effects of temperature (30-70 degrees C), enzyme concentration (2.5-18 wt %), Triton X-100 concentration (10-20 wt %), and glycerol to oil molar ratio (3:1, 6:1, and 9:1). Experimental results showed that lipase-catalyzed solvent-free glycerolysis with the addition of Triton X-100 might be a potential alternative route to conventional organic solvent methods, as good conversions were obtained with relatively low enzyme concentrations (9 wt %) in short reaction times (240 min). The glycerolysis and hydrolysis parallel reactions were considered with rate constants estimated by minimizing a maximum likelihood function. A very satisfactory agreement between experimental data and model results was obtained, thus allowing a better understanding of the reaction kinetics." @default.
• W2080608344 created "2016-06-24" @default.
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• W2080608344 date "2009-09-23" @default.
• W2080608344 modified "2023-10-01" @default.
• W2080608344 title "Kinetics of Solvent-Free Lipase-Catalyzed Glycerolysis of Olive Oil in Surfactant System" @default.
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• W2080608344 doi "https://doi.org/10.1021/jf901771m" @default.
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