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• W2080632174 abstract "Abstract A novel biomimetic membrane made of conducting polymer (CP) film with dispersed biological ligands (BL) is described. Adenosine diphosphate (ADP), which serves as BL, is invited as a dopant into the CP matrix formed by poly(ethylene 3,4 dioxythiophene) (PEDOT) during electropolymerization. The PEDOT–ADP films are characterized with scanning electron microscopy (SEM), energy dispersive X-ray (EDAX) and atomic force microscopy (AFM). Films are made sensitive to divalent cations (Ca 2+ or Mg 2+ ) with an optimized electrochemical oxidation and soaking processes. Resulting close-to-Nernstian potentiometric slopes are observed. Transitory potentials for the PEDOT–ADP films are studied with open-circuit measurements. Distinctively different responses for the bulk concentration changes of Ca 2+ or Mg 2+ ions are ascribed to a competitive ion-exchange process on the ADP sites." @default.
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• W2080632174 date "2012-08-01" @default.
• W2080632174 modified "2023-09-23" @default.
• W2080632174 title "Biomimetic membranes made of conducting polymers doped with adenosine diphosphate (ADP)" @default.
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• W2080632174 doi "https://doi.org/10.1016/j.electacta.2012.04.058" @default.
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