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- W2080648644 abstract "A series of aryl-substituted 1,3-dithiol-2-ones was prepared by the BhattacharyaHortmann cyclization method. Unexpectedly, a Ritter reaction occurred during the acid-catalyzed cyclization at the cyano group of the aryl substituents and 1,3-dithiol-2-ones bearing a carboxy or a carboxamide group could be selectively obtained (see 1 and 2a in Scheme 1). The formation of the acid or the amide functionality was temperature-dependent so that the one or the other group could be introduced selectively by modifying the reaction temperature." @default.
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- W2080648644 date "2013-05-01" @default.
- W2080648644 modified "2023-09-27" @default.
- W2080648644 title "UnexpectedRitterReaction During Acid-Promoted 1,3-Dithiol-2-one Formation" @default.
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- W2080648644 doi "https://doi.org/10.1002/hlca.201200311" @default.
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