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- W2080650942 abstract "Two pairs of enantiomerically pure three-dimensional (3D) chiral polyoxometalate (POM) framework materials L,D-[K(H2O)]6·[H2GeW12O40]3·35H2O (1a and 1b) and L,D-[K(H2O)]6·[H2SiW12O40]3·29H2O (2a and 2b) based on inorganic achiral building blocks, have been synthesized and characterized by X-ray crystallography, elemental analysis, powder X-ray diffraction (PXRD), UV-Vis spectroscopy, circular dichroism (CD) spectra. Single-crystal X-ray diffraction analyses revealed that 1a and 1b, 2a and 2b are enantiomers, respectively. In 1a and 1b, 2a and 2b, {K(H2O)}n link terminal oxygen and μ2-bridging oxygen of Keggin-type polyanion moieties to generate 1D 31 helical infinite chiral chains, which are further connected by the achiral Keggin-type polyoxoanions to form 3D 4,8-connected chiral self-assembly frameworks with {412·610·86}{46}2 topology. 1 and 2 are isostructural. They are obtained by spontaneous resolution upon crystallization in the absence of any chiral source. They represent new examples of chiral self-penetrating pure inorganic frameworks known for POM systems. Compounds 1 and 2 display adsorption activity toward volatile organic compounds (VOCs)." @default.
- W2080650942 created "2016-06-24" @default.
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- W2080650942 date "2013-01-01" @default.
- W2080650942 modified "2023-09-26" @default.
- W2080650942 title "Assembly and spontaneous resolution of the chiral inorganic polyoxometalates-based frameworks via helical chains association" @default.
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- W2080650942 doi "https://doi.org/10.1039/c3dt50672j" @default.
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