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- W2080651505 abstract "By increasing the size of the alkylammonium countercation, it is possible to tune the reaction product obtained from a mixture of cobalt sulfate, citric acid and tetraalkylammonium hydroxide in aqueous solution at pH = 6; products range from a double salt [NR4]2[Co(H2O)6][SO4]2·4H2O containing water hexamers (R = Me) or 1-D water chains (R = Et) to a new cobalt(II) citrate 1-D coordination polymer [NBu4]2[Co2(Hcit)2(H2O)4]·4H2O. Increasing the size of the cation results in a corresponding decrease in the dimensionality of the water motifs, from a 3-D network when R = Me, to a 2-D lattice when R = Et and a 1-D lattice when R = Bu." @default.
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- W2080651505 date "2006-01-01" @default.
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- W2080651505 title "Tuning the structural motif by tuning the countercation size: from double salts to a 1-D coordination polymer" @default.
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- W2080651505 doi "https://doi.org/10.1039/b600447d" @default.
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