FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080657139> ?p ?o ?g. }

• W2080657139 endingPage "7431" @default.
• W2080657139 startingPage "7422" @default.
• W2080657139 abstract "AuCl4- ions are transformed into Au crystallites via two consecutive photoreactions inside cross-linked polymers of diallyldimethylammonium chloride swollen with methanol. The photoreactions are markedly influenced by the gel matrix, which facilitates pathways not observed in homogeneous solutions and controls the direction of propagation. Initially, the reactions are repressed by air, but at longer times they are aided by products from the O2-reduction. The first process is an efficient monophotonic chain reduction of AuCl4- with chain lengths in excess of 80 and an atypical pseudofirst-order termination. Kinetic data from fully swollen gels is understood in terms of a mechanism involving solution reactions of ·CH2OH radical chain carriers. Light-absorbing products of the first photoreaction, believed to be gold clusters, initiate the second process that yields metal particles. Several common kinetic features are displayed by both photoreactions. However, generation of Au crystallites takes place via an unusual biphotonic chain reaction, with reaction rates that are correlated to the number of particle formation and decay cycles." @default.
• W2080657139 created "2016-06-24" @default.
• W2080657139 creator A5022436038 @default.
• W2080657139 creator A5036686569 @default.
• W2080657139 creator A5038228174 @default.
• W2080657139 creator A5061877239 @default.
• W2080657139 creator A5065750900 @default.
• W2080657139 creator A5068814338 @default.
• W2080657139 date "2002-07-09" @default.
• W2080657139 modified "2023-09-26" @default.
• W2080657139 title "Formation Kinetics of Small Gold Crystallites in Photoresponsive Polymer Gels" @default.
• W2080657139 cites W1556801875 @default.
• W2080657139 cites W1963689285 @default.
• W2080657139 cites W1968573363 @default.
• W2080657139 cites W1968958940 @default.
• W2080657139 cites W1975586641 @default.
• W2080657139 cites W1976624408 @default.
• W2080657139 cites W1980474669 @default.
• W2080657139 cites W1981021899 @default.
• W2080657139 cites W1986733718 @default.
• W2080657139 cites W1987520979 @default.
• W2080657139 cites W1995173156 @default.
• W2080657139 cites W1996818029 @default.
• W2080657139 cites W2005807385 @default.
• W2080657139 cites W2021236516 @default.
• W2080657139 cites W2024842423 @default.
• W2080657139 cites W2027302696 @default.
• W2080657139 cites W2027442225 @default.
• W2080657139 cites W2030125126 @default.
• W2080657139 cites W2037020209 @default.
• W2080657139 cites W2048917513 @default.
• W2080657139 cites W2052197848 @default.
• W2080657139 cites W2067667072 @default.
• W2080657139 cites W2074303530 @default.
• W2080657139 cites W2080207106 @default.
• W2080657139 cites W2080815582 @default.
• W2080657139 cites W2097241821 @default.
• W2080657139 cites W2130141146 @default.
• W2080657139 cites W2132449311 @default.
• W2080657139 cites W2319677115 @default.
• W2080657139 cites W2478090614 @default.
• W2080657139 cites W2615152981 @default.
• W2080657139 cites W2950632530 @default.
• W2080657139 cites W4299446907 @default.
• W2080657139 cites W567912678 @default.
• W2080657139 doi "https://doi.org/10.1021/jp020176i" @default.
• W2080657139 hasPublicationYear "2002" @default.
• W2080657139 type Work @default.
• W2080657139 sameAs 2080657139 @default.
• W2080657139 citedByCount "39" @default.
• W2080657139 countsByYear W20806571392013 @default.
• W2080657139 countsByYear W20806571392014 @default.
• W2080657139 countsByYear W20806571392016 @default.
• W2080657139 countsByYear W20806571392017 @default.
• W2080657139 countsByYear W20806571392018 @default.
• W2080657139 countsByYear W20806571392019 @default.
• W2080657139 crossrefType "journal-article" @default.
• W2080657139 hasAuthorship W2080657139A5022436038 @default.
• W2080657139 hasAuthorship W2080657139A5036686569 @default.
• W2080657139 hasAuthorship W2080657139A5038228174 @default.
• W2080657139 hasAuthorship W2080657139A5061877239 @default.
• W2080657139 hasAuthorship W2080657139A5065750900 @default.
• W2080657139 hasAuthorship W2080657139A5068814338 @default.
• W2080657139 hasConcept C121332964 @default.
• W2080657139 hasConcept C127413603 @default.
• W2080657139 hasConcept C1276947 @default.
• W2080657139 hasConcept C135889238 @default.
• W2080657139 hasConcept C137637335 @default.
• W2080657139 hasConcept C145148216 @default.
• W2080657139 hasConcept C148898269 @default.
• W2080657139 hasConcept C166940927 @default.
• W2080657139 hasConcept C178790620 @default.
• W2080657139 hasConcept C185592680 @default.
• W2080657139 hasConcept C188027245 @default.
• W2080657139 hasConcept C199185054 @default.
• W2080657139 hasConcept C2778695967 @default.
• W2080657139 hasConcept C38087914 @default.
• W2080657139 hasConcept C42360764 @default.
• W2080657139 hasConcept C521977710 @default.
• W2080657139 hasConcept C544153396 @default.
• W2080657139 hasConcept C62520636 @default.
• W2080657139 hasConcept C66882249 @default.
• W2080657139 hasConcept C75473681 @default.
• W2080657139 hasConcept C8010536 @default.
• W2080657139 hasConcept C97355855 @default.
• W2080657139 hasConceptScore W2080657139C121332964 @default.
• W2080657139 hasConceptScore W2080657139C127413603 @default.
• W2080657139 hasConceptScore W2080657139C1276947 @default.
• W2080657139 hasConceptScore W2080657139C135889238 @default.
• W2080657139 hasConceptScore W2080657139C137637335 @default.
• W2080657139 hasConceptScore W2080657139C145148216 @default.
• W2080657139 hasConceptScore W2080657139C148898269 @default.
• W2080657139 hasConceptScore W2080657139C166940927 @default.
• W2080657139 hasConceptScore W2080657139C178790620 @default.
• W2080657139 hasConceptScore W2080657139C185592680 @default.
• W2080657139 hasConceptScore W2080657139C188027245 @default.
• W2080657139 hasConceptScore W2080657139C199185054 @default.
• W2080657139 hasConceptScore W2080657139C2778695967 @default.

• next