FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080683144> ?p ?o ?g. }

• W2080683144 endingPage "23" @default.
• W2080683144 startingPage "13" @default.
• W2080683144 abstract "The conformation of the oxidation product (A) of biruthenocene (RcRc) with p-benzoquinone containing boron trifluoride diethylether complex is [RcRcC6H4O2]2+(BF4−)2 in which p-benzoquinoen is ligated to the RuIV center. The recrystallization of A from the mixture of nitromethhane containing small amount of acetonitrile or pyrazine gives mixed-valence cations formulated as [RuIICp(C5H4C5H4)CpRuIVL]2+ (L = acetonitrile 1 and pyrazine 2), in which L is coordinated to the RuIV center. The crystal of 1 formulated as [RuIICp(C5H4C5H4)CpRuIVNCCH3]2+ (BF4−)2. CH3NO2 (1), is found to be orthorhombic, space group Pbca, a = 14.255(7), b = 37.105(10), c = 10.051(4) Å, V = 5316(4), Z = 8 and the final R = 0.054 and Rw = 0.059. The similar pyrazine salt 2 formulated as [RuIICp(C5H4C5H4)CpRuIVN(CH)4N]2+ (BF4−)2(CH3NO2)2is found to be triclinic, space group P1, a = 9.006(2), b = 19.233(4), c = 28.907(10) Å, α = 89.45(1)°, β = 86.10(3)°, γ = 87.85(2)°, V = 4991(2), Z = 2, and the final R = 0.077 and RW = 0.090. The unit cell has three independent molecules (2A, 2B, 2C). The Ru(IV)-N distances (2.15(1) Å for 2A, 2.11(1) for 2B and 2.15(1) for 2C) are longer by ca. 0.1 Å than that of 1 because of bulky molecule of pyrazine. Both cations (1,2) have wedge-sharp structure due to the RuN bond, the dihedral angles between the Cp and C5H4 rings of the [LRuIVCp(C5H4)]2+ moiety are 38.70° for 1, 38.77° (2A), 40.84° (2B) and 41.67° (2C) for 2. The nucleophilicity to the RuIV increases in the order Cl− > pyrazine > acetoritrile > p-benzoquinone and unlike the case of mixed-valence halobiruthenocenium cations ([RcRcX]+: X  Cl, Br, I), no temperature dependent 1H - and 13C-NMR spectra were observed for 1 and 2 in solution, implying the absence of two-electron exchange reaction between the RuII and RuIV." @default.
• W2080683144 created "2016-06-24" @default.
• W2080683144 creator A5040778839 @default.
• W2080683144 creator A5042311507 @default.
• W2080683144 creator A5044317906 @default.
• W2080683144 creator A5069168579 @default.
• W2080683144 date "1997-12-01" @default.
• W2080683144 modified "2023-10-14" @default.
• W2080683144 title "A molecular structure of mixed valence biruthenocenium (RuIIRuIV) salts [RuIICp(C5H4C5H4)CpRuIVL]2+(BF4−)2 (L  NCCH3, N(CH)4N)" @default.
• W2080683144 cites W1963486098 @default.
• W2080683144 cites W1965412259 @default.
• W2080683144 cites W1971722087 @default.
• W2080683144 cites W1979393860 @default.
• W2080683144 cites W1982753726 @default.
• W2080683144 cites W1983718518 @default.
• W2080683144 cites W1996829969 @default.
• W2080683144 cites W1998792838 @default.
• W2080683144 cites W2003938276 @default.
• W2080683144 cites W2004295868 @default.
• W2080683144 cites W2009302661 @default.
• W2080683144 cites W2012190624 @default.
• W2080683144 cites W2013224988 @default.
• W2080683144 cites W2015135121 @default.
• W2080683144 cites W2022041138 @default.
• W2080683144 cites W2026250273 @default.
• W2080683144 cites W2034402791 @default.
• W2080683144 cites W2043002533 @default.
• W2080683144 cites W2044345012 @default.
• W2080683144 cites W2044931258 @default.
• W2080683144 cites W2051086263 @default.
• W2080683144 cites W2051950375 @default.
• W2080683144 cites W2054831033 @default.
• W2080683144 cites W2060834586 @default.
• W2080683144 cites W2070650749 @default.
• W2080683144 cites W2078176753 @default.
• W2080683144 cites W2131502598 @default.
• W2080683144 cites W2145994959 @default.
• W2080683144 cites W2153403350 @default.
• W2080683144 cites W2166052839 @default.
• W2080683144 cites W2343082826 @default.
• W2080683144 cites W2469373751 @default.
• W2080683144 cites W2952811866 @default.
• W2080683144 cites W3137560359 @default.
• W2080683144 doi "https://doi.org/10.1016/s0022-328x(97)00230-1" @default.
• W2080683144 hasPublicationYear "1997" @default.
• W2080683144 type Work @default.
• W2080683144 sameAs 2080683144 @default.
• W2080683144 citedByCount "10" @default.
• W2080683144 countsByYear W20806831442013 @default.
• W2080683144 countsByYear W20806831442016 @default.
• W2080683144 countsByYear W20806831442018 @default.
• W2080683144 crossrefType "journal-article" @default.
• W2080683144 hasAuthorship W2080683144A5040778839 @default.
• W2080683144 hasAuthorship W2080683144A5042311507 @default.
• W2080683144 hasAuthorship W2080683144A5044317906 @default.
• W2080683144 hasAuthorship W2080683144A5069168579 @default.
• W2080683144 hasConcept C112887158 @default.
• W2080683144 hasConcept C115624301 @default.
• W2080683144 hasConcept C155647269 @default.
• W2080683144 hasConcept C168900304 @default.
• W2080683144 hasConcept C178790620 @default.
• W2080683144 hasConcept C185592680 @default.
• W2080683144 hasConcept C2777463227 @default.
• W2080683144 hasConcept C2777765701 @default.
• W2080683144 hasConcept C32909587 @default.
• W2080683144 hasConcept C37243968 @default.
• W2080683144 hasConcept C42228675 @default.
• W2080683144 hasConcept C71240020 @default.
• W2080683144 hasConcept C8010536 @default.
• W2080683144 hasConcept C89025888 @default.
• W2080683144 hasConceptScore W2080683144C112887158 @default.
• W2080683144 hasConceptScore W2080683144C115624301 @default.
• W2080683144 hasConceptScore W2080683144C155647269 @default.
• W2080683144 hasConceptScore W2080683144C168900304 @default.
• W2080683144 hasConceptScore W2080683144C178790620 @default.
• W2080683144 hasConceptScore W2080683144C185592680 @default.
• W2080683144 hasConceptScore W2080683144C2777463227 @default.
• W2080683144 hasConceptScore W2080683144C2777765701 @default.
• W2080683144 hasConceptScore W2080683144C32909587 @default.
• W2080683144 hasConceptScore W2080683144C37243968 @default.
• W2080683144 hasConceptScore W2080683144C42228675 @default.
• W2080683144 hasConceptScore W2080683144C71240020 @default.
• W2080683144 hasConceptScore W2080683144C8010536 @default.
• W2080683144 hasConceptScore W2080683144C89025888 @default.
• W2080683144 hasIssue "1-2" @default.
• W2080683144 hasLocation W20806831441 @default.
• W2080683144 hasOpenAccess W2080683144 @default.
• W2080683144 hasPrimaryLocation W20806831441 @default.
• W2080683144 hasRelatedWork W147098589 @default.
• W2080683144 hasRelatedWork W2037441916 @default.
• W2080683144 hasRelatedWork W2094957800 @default.
• W2080683144 hasRelatedWork W2360134566 @default.
• W2080683144 hasRelatedWork W2498889807 @default.
• W2080683144 hasRelatedWork W2563074422 @default.
• W2080683144 hasRelatedWork W2902603126 @default.
• W2080683144 hasRelatedWork W4200547711 @default.
• W2080683144 hasRelatedWork W4249168586 @default.
• W2080683144 hasRelatedWork W2525935488 @default.

• next