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- W2080684608 abstract "This work investigates the Mn 2+ electronic structure and photoluminescence (PL) in [(CH 3)4N]MnCl 3 (TMMC) and their variation with pressure by time-resolved excitation and emission measurements in the 0–15 GPa range. We show that both the crystal-field excitation and the corresponding PL bands experience large pressure redshifts, which are associated with the anisotropic crystal compressibility providing large axial ligand fields at the Mn 2+ site in TMMC. These variations are very large for the emission band, which shifts with pressure at a rate of 21 nm/GPa (50 meV/GPa), making TMMC suitable for using as a pressure gauge. We show that TMMC provides precise pressure determinations in low pressure ranges (MPa–GPa), since it has the capability to detect pressure variations of 10 MPa." @default.
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- W2080684608 date "2009-12-01" @default.
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- W2080684608 title "Spectroscopic and luminescence properties of (CH<sub>3</sub>)<sub>4</sub>NMnCl<sub>3</sub>: a sensitive Mn<sup>2+</sup>-based pressure gauge" @default.
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- W2080684608 doi "https://doi.org/10.1080/08957950903414979" @default.
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