Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080691672> ?p ?o ?g. }
- W2080691672 endingPage "4795" @default.
- W2080691672 startingPage "4790" @default.
- W2080691672 abstract "The translational diffusion constants, D, of trans-stilbene, 1,4-dipheny-1,3-butadiene, 1,6-dipheny-1,3,5-hexatriene, 1,1,4,4,-tetraphenyl-1,3-butadiene, tetraphenylethylene, 9,10-diphenylanthracene, p-terphenyl, bibenzyl, 1,1‘-binaphthyl, [2.2]paracyclophane, triptycene, and dodecahydrotriphenylene have been determined in the n-alkanes using capillary flow techniques. The solutes showed deviations from the Stokes−Einstein (SE) relation (D = kBT/(6πηr)); the values of the hydrodynamic radius, r, decrease as the viscosity, η, increases. The data can be fitted to D/T = ASE/ηp with p < 1 (p = 1 for the SE relation). The values of p increase as the solute size increases; they range from p = 0.712 for p-terphenyl to p = 0.942 for 1,1,4,4,-tetraphenyl-1,3-butadiene. The deviations from SE behavior are discussed in terms of the ratio Vs/Vp, where Vs and Vp are the van der Waals volumes of a solvent and diffusing probe, respectively. The diffusion constants also are discussed in terms of the Wilke−Chang equation. The values of D-1 for several of the solutes are compared with their rotational correlation times, τθ, in the n-alkanes. The values of τθ, which showed deviations from the Stokes−Einstein−Debye expression (τθ = 4πr3η/(3kBT)), have the same general dependence on viscosity as D-1." @default.
- W2080691672 created "2016-06-24" @default.
- W2080691672 creator A5025641758 @default.
- W2080691672 creator A5033043174 @default.
- W2080691672 creator A5041047095 @default.
- W2080691672 creator A5048437410 @default.
- W2080691672 creator A5059689540 @default.
- W2080691672 creator A5066567919 @default.
- W2080691672 date "2003-05-28" @default.
- W2080691672 modified "2023-09-27" @default.
- W2080691672 title "Size-Dependent Diffusion in the <i>n</i>-Alkanes" @default.
- W2080691672 cites W1964691144 @default.
- W2080691672 cites W1965910429 @default.
- W2080691672 cites W1969443497 @default.
- W2080691672 cites W1971567218 @default.
- W2080691672 cites W1972386486 @default.
- W2080691672 cites W1973207448 @default.
- W2080691672 cites W1981622267 @default.
- W2080691672 cites W1984320254 @default.
- W2080691672 cites W1987014906 @default.
- W2080691672 cites W1987218125 @default.
- W2080691672 cites W1987597484 @default.
- W2080691672 cites W1993327079 @default.
- W2080691672 cites W2001872153 @default.
- W2080691672 cites W2009395737 @default.
- W2080691672 cites W2018031319 @default.
- W2080691672 cites W2020747116 @default.
- W2080691672 cites W2026283460 @default.
- W2080691672 cites W2027012866 @default.
- W2080691672 cites W2028450569 @default.
- W2080691672 cites W2030841140 @default.
- W2080691672 cites W2033408795 @default.
- W2080691672 cites W2041616107 @default.
- W2080691672 cites W2043930694 @default.
- W2080691672 cites W2046232190 @default.
- W2080691672 cites W2046464995 @default.
- W2080691672 cites W2048527574 @default.
- W2080691672 cites W2066244281 @default.
- W2080691672 cites W2068163887 @default.
- W2080691672 cites W2068780626 @default.
- W2080691672 cites W2078359000 @default.
- W2080691672 cites W2080634539 @default.
- W2080691672 cites W2083170144 @default.
- W2080691672 cites W2084412823 @default.
- W2080691672 cites W2127730853 @default.
- W2080691672 cites W2152783510 @default.
- W2080691672 cites W2155275563 @default.
- W2080691672 cites W4244169112 @default.
- W2080691672 cites W4254056711 @default.
- W2080691672 doi "https://doi.org/10.1021/jp022470g" @default.
- W2080691672 hasPublicationYear "2003" @default.
- W2080691672 type Work @default.
- W2080691672 sameAs 2080691672 @default.
- W2080691672 citedByCount "24" @default.
- W2080691672 countsByYear W20806916722013 @default.
- W2080691672 countsByYear W20806916722014 @default.
- W2080691672 countsByYear W20806916722016 @default.
- W2080691672 countsByYear W20806916722021 @default.
- W2080691672 countsByYear W20806916722022 @default.
- W2080691672 crossrefType "journal-article" @default.
- W2080691672 hasAuthorship W2080691672A5025641758 @default.
- W2080691672 hasAuthorship W2080691672A5033043174 @default.
- W2080691672 hasAuthorship W2080691672A5041047095 @default.
- W2080691672 hasAuthorship W2080691672A5048437410 @default.
- W2080691672 hasAuthorship W2080691672A5059689540 @default.
- W2080691672 hasAuthorship W2080691672A5066567919 @default.
- W2080691672 hasConcept C11268172 @default.
- W2080691672 hasConcept C113196181 @default.
- W2080691672 hasConcept C121332964 @default.
- W2080691672 hasConcept C127172972 @default.
- W2080691672 hasConcept C147789679 @default.
- W2080691672 hasConcept C178790620 @default.
- W2080691672 hasConcept C184651966 @default.
- W2080691672 hasConcept C185592680 @default.
- W2080691672 hasConcept C207374878 @default.
- W2080691672 hasConcept C2779394022 @default.
- W2080691672 hasConcept C43617362 @default.
- W2080691672 hasConcept C69357855 @default.
- W2080691672 hasConcept C97355855 @default.
- W2080691672 hasConceptScore W2080691672C11268172 @default.
- W2080691672 hasConceptScore W2080691672C113196181 @default.
- W2080691672 hasConceptScore W2080691672C121332964 @default.
- W2080691672 hasConceptScore W2080691672C127172972 @default.
- W2080691672 hasConceptScore W2080691672C147789679 @default.
- W2080691672 hasConceptScore W2080691672C178790620 @default.
- W2080691672 hasConceptScore W2080691672C184651966 @default.
- W2080691672 hasConceptScore W2080691672C185592680 @default.
- W2080691672 hasConceptScore W2080691672C207374878 @default.
- W2080691672 hasConceptScore W2080691672C2779394022 @default.
- W2080691672 hasConceptScore W2080691672C43617362 @default.
- W2080691672 hasConceptScore W2080691672C69357855 @default.
- W2080691672 hasConceptScore W2080691672C97355855 @default.
- W2080691672 hasIssue "24" @default.
- W2080691672 hasLocation W20806916721 @default.
- W2080691672 hasOpenAccess W2080691672 @default.
- W2080691672 hasPrimaryLocation W20806916721 @default.
- W2080691672 hasRelatedWork W1964442284 @default.
- W2080691672 hasRelatedWork W1995987412 @default.