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- W2080697692 abstract "3-Methyl-substituted 1-phosphanorbornadiene oxides or sulfides such as 1a,b are either metalated by a strong base (n-BuLi or LDA) or brominated by NBS at the methyl substituent. The reaction of the resulting delocalised carbanions 2a,b takes place either at C-2 (H+, MeI) or at the methylene group (Me3SiCl, ClPPh2, I2). In the last case, γ-functional (5a,b or 6a,b) or bridged (7) phosphanorbornadienes are obtained. Similarly, the reaction of 3-bromomethyl-1-phosphanorbornadiene oxides such as 8 with nucleophiles [NaCH(CO2Me)2, PhO–, Me2NH, PhCH2NH2] yields the corresponding γ-functional phosphanorbornadienes 9–12. This chemistry has also been applied to the BIPNOR dioxide 13." @default.
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- W2080697692 date "1999-05-01" @default.
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- W2080697692 title "γ-Functionalisation of the 1-Phosphanorbornadiene Structure" @default.
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