FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080702119> ?p ?o ?g. }

• W2080702119 endingPage "541" @default.
• W2080702119 startingPage "511" @default.
• W2080702119 abstract "Building on the linear network thermodynamic model presented in the first paper in this series (Mikulecky, Wiegand & Shiner, 1977), a method of non-linear analysis is developed based mainly on the methods of Chua (1969). Using coupled salt and volume flow through membranes as an example, it is shown that the Kedem & Katchalsky (1963a,b,c) linear model of series combinations of membranes behaves in a physically unrealistic manner (negative and infinite concentrations occur in the compartment between the membranes). Using the model introduced by Patlak, Goldstein & Hoffman (1963) to obtain characteristics for a non-linear 2-port, the series network is well behaved and self-regulated. In the coordinate system of the linear reciprocal 2-port, the non-linear 2-port is shown to be a non-reciprocal element. Another co-ordinate system, which utilizes unidirectional fluxes (as measured by isotope fluxes, for example) and their conjugate driving forces, shows the non-linear 2-port to be separable in the sense of Li (1962) and Rosen (1968). A set of three pseudo-independent force-flow pairs completely characterizes the system and is compatible with a very simple non-linear network analysis which utilizes experimentally accessible and practical parameters such as the unidirectional solute fluxes, concentrations in the baths, volume flow and the hydrostatic minus effective osmotic pressure. As constitutive relations, the forward and backward permeabilities, which are dependent on volume flow and the filtration coefficient are all that are needed. A reflection coefficient appears in the driving force conjugate to volume flow in that the effective osmotic pressure is δΔπ and thus four independent coefficients, two of which depend on volume flow, are needed to determine the system. From the network analysis, the global properties of the series and/or parallel combinations of non-linear 2-ports are readily obtained. Although applied to a particular example, these non-linear methods are perfectly general. They are essentially the graphical form of the algebraic analysis in the linear theory, and are essentially based on the generalized version of Kirchhoff's laws used in graph and network theory. In the particular case of coupled solute and volume flow through membranes the non-linear element has a natural piecewise linearization which allows the linear theory to be applied using different values for the elements in each region. In an initial analysis, a linear network is drawn using the I-equivalent network of 1-port elements to model the linear 2-port in a series system. From this over-simplication a great deal of the qualitative behavior of the system can be visualized. For example, it is an easy way to see that solute will be accumulated or depleted in the central compartment between the membranes in an asymmetric series system. After this the non-linear analysis is used to further quantitatively describe the system's behavior and such phenomena as rectification of volume flow in the series membrane system. An appendix introduces a general theory for a class of non-linear transport phenomena." @default.
• W2080702119 created "2016-06-24" @default.
• W2080702119 creator A5081203023 @default.
• W2080702119 date "1977-12-01" @default.
• W2080702119 modified "2023-10-18" @default.
• W2080702119 title "A simple network thermodynamic method for series-parallel coupled flows II. The non-linear theory, with applications to coupled solute and volume flow in a series membrane" @default.
• W2080702119 cites W1964163154 @default.
• W2080702119 cites W1964948652 @default.
• W2080702119 cites W1966198294 @default.
• W2080702119 cites W1973846863 @default.
• W2080702119 cites W1981053893 @default.
• W2080702119 cites W1989099906 @default.
• W2080702119 cites W1990483059 @default.
• W2080702119 cites W1996478096 @default.
• W2080702119 cites W2024013770 @default.
• W2080702119 cites W2033061643 @default.
• W2080702119 cites W2045385623 @default.
• W2080702119 cites W2054444405 @default.
• W2080702119 cites W2055604322 @default.
• W2080702119 cites W2058191865 @default.
• W2080702119 cites W2060426337 @default.
• W2080702119 cites W2067600528 @default.
• W2080702119 cites W2087024584 @default.
• W2080702119 cites W2087600078 @default.
• W2080702119 cites W2090885055 @default.
• W2080702119 cites W2129012818 @default.
• W2080702119 cites W2152770779 @default.
• W2080702119 cites W2163465718 @default.
• W2080702119 cites W2886407910 @default.
• W2080702119 cites W2919982685 @default.
• W2080702119 cites W4233985421 @default.
• W2080702119 cites W4241671624 @default.
• W2080702119 doi "https://doi.org/10.1016/0022-5193(77)90154-0" @default.
• W2080702119 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/607019" @default.
• W2080702119 hasPublicationYear "1977" @default.
• W2080702119 type Work @default.
• W2080702119 sameAs 2080702119 @default.
• W2080702119 citedByCount "37" @default.
• W2080702119 countsByYear W20807021192018 @default.
• W2080702119 countsByYear W20807021192021 @default.
• W2080702119 countsByYear W20807021192023 @default.
• W2080702119 crossrefType "journal-article" @default.
• W2080702119 hasAuthorship W2080702119A5081203023 @default.
• W2080702119 hasConcept C121332964 @default.
• W2080702119 hasConcept C127313418 @default.
• W2080702119 hasConcept C134306372 @default.
• W2080702119 hasConcept C134853933 @default.
• W2080702119 hasConcept C143724316 @default.
• W2080702119 hasConcept C151730666 @default.
• W2080702119 hasConcept C158622935 @default.
• W2080702119 hasConcept C20556612 @default.
• W2080702119 hasConcept C33923547 @default.
• W2080702119 hasConcept C38349280 @default.
• W2080702119 hasConcept C57879066 @default.
• W2080702119 hasConcept C62520636 @default.
• W2080702119 hasConcept C6802819 @default.
• W2080702119 hasConcept C97355855 @default.
• W2080702119 hasConceptScore W2080702119C121332964 @default.
• W2080702119 hasConceptScore W2080702119C127313418 @default.
• W2080702119 hasConceptScore W2080702119C134306372 @default.
• W2080702119 hasConceptScore W2080702119C134853933 @default.
• W2080702119 hasConceptScore W2080702119C143724316 @default.
• W2080702119 hasConceptScore W2080702119C151730666 @default.
• W2080702119 hasConceptScore W2080702119C158622935 @default.
• W2080702119 hasConceptScore W2080702119C20556612 @default.
• W2080702119 hasConceptScore W2080702119C33923547 @default.
• W2080702119 hasConceptScore W2080702119C38349280 @default.
• W2080702119 hasConceptScore W2080702119C57879066 @default.
• W2080702119 hasConceptScore W2080702119C62520636 @default.
• W2080702119 hasConceptScore W2080702119C6802819 @default.
• W2080702119 hasConceptScore W2080702119C97355855 @default.
• W2080702119 hasIssue "3" @default.
• W2080702119 hasLocation W20807021191 @default.
• W2080702119 hasLocation W20807021192 @default.
• W2080702119 hasOpenAccess W2080702119 @default.
• W2080702119 hasPrimaryLocation W20807021191 @default.
• W2080702119 hasRelatedWork W1966522846 @default.
• W2080702119 hasRelatedWork W1971821897 @default.
• W2080702119 hasRelatedWork W1977961233 @default.
• W2080702119 hasRelatedWork W2042415396 @default.
• W2080702119 hasRelatedWork W2092793634 @default.
• W2080702119 hasRelatedWork W2104924885 @default.
• W2080702119 hasRelatedWork W2325664614 @default.
• W2080702119 hasRelatedWork W234788982 @default.
• W2080702119 hasRelatedWork W3033558109 @default.
• W2080702119 hasRelatedWork W4313276337 @default.
• W2080702119 hasVolume "69" @default.
• W2080702119 isParatext "false" @default.
• W2080702119 isRetracted "false" @default.
• W2080702119 magId "2080702119" @default.
• W2080702119 workType "article" @default.