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- W2080705172 abstract "The synthesis of a novel hybrid pyrazolate/phosphine anionic ligand [CH2CHCH2B(CH2PPh2)(pz)2]- is described. Coordination of this ligand to metals in a fac tridentate fashion occurs in the complexes [CH2CHCH2B(CH2PPh2)(pz)2M(cod)], prepared by reactions of the lithium salt of the ligand with [M(μ-Cl)(cod)]2 (M = Rh, Ir). They are pentacoordinated, with the rhodium complex showing a distorted trigonal-bipyramidal structure in the solid state, as determined by X-ray diffraction methods. Furthermore, the ligand has been linked to the periphery of a carbosilane dendrimer, resulting in the polyanionic dendrimer [Li(TMED)]4[Si{(CH2)3SiMe2(CH2)3B(CH2PPh2)(pz)2}4], which leads further to the corresponding metallodendrimer with four rhodium atoms." @default.
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- W2080705172 date "2005-10-25" @default.
- W2080705172 modified "2023-10-02" @default.
- W2080705172 title "Unprecedented Hybrid Scorpionate/Phosphine Ligand Able To Be Anchored to Carbosilane Dendrimers" @default.
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- W2080705172 doi "https://doi.org/10.1021/ic051279t" @default.
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