FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080740075> ?p ?o ?g. }

• W2080740075 endingPage "6587" @default.
• W2080740075 startingPage "6577" @default.
• W2080740075 abstract "The ground state Ka =0(u)→1(g) b-type subband of the rotation–tunneling spectrum of the symmetric 35Cl–35Cl, 37Cl–37Cl, and the mixed 35Cl–37Cl hydrogen chloride dimers have been recorded near 26.3 cm−1 with sub-Doppler resolution in a continuous two-dimensional supersonic jet with a tunable far-infrared laser spectrometer. Quadrupole hyperfine structure from the chlorine nuclei has been resolved. From the fitted rotational constants a (H35Cl)2 center-of-mass separation of 3.81 Å is derived for the Ka =1(g) levels, while the nuclear quadrupole coupling constants yield a vibrationally averaged angular structure for both tunneling states of approximately 20–25 deg for the hydrogen bonded proton and at least 70–75 deg for the external proton. This nearly orthogonal structure agrees well with that predicted by ab initio theoretical calculations, but the observed splittings and intensity alterations of the lines indicate that the chlorine nuclei are made equivalent by a large amplitude tunneling motion of the HCl monomers. A similar geared internal rotation tunneling motion has been found for the HF dimer, but here the effect is much greater. The ground state tunneling splittings are estimated to lie between 15–18 cm−1, and the selection rules observed indicate that the trans tunneling path dominates the large amplitude motion, as expected, provided the dimer remains planar. From the observed hyperfine constants, we judge the dimer and its associated tunneling motion to be planar to within 10°." @default.
• W2080740075 created "2016-06-24" @default.
• W2080740075 creator A5004149083 @default.
• W2080740075 creator A5028330542 @default.
• W2080740075 creator A5037746247 @default.
• W2080740075 creator A5069188516 @default.
• W2080740075 creator A5075279360 @default.
• W2080740075 creator A5076662158 @default.
• W2080740075 date "1988-12-01" @default.
• W2080740075 modified "2023-10-16" @default.
• W2080740075 title "Tunable far-infrared laser spectroscopy of hydrogen bonds: The <i>K</i> <i>a</i> =0(<i>u</i>)→1(<i>g</i>) rotation–tunneling spectrum of the HCl dimer" @default.
• W2080740075 cites W1779357548 @default.
• W2080740075 cites W1968363588 @default.
• W2080740075 cites W1975095425 @default.
• W2080740075 cites W1983822919 @default.
• W2080740075 cites W1997662998 @default.
• W2080740075 cites W1997741454 @default.
• W2080740075 cites W2000278981 @default.
• W2080740075 cites W2001787100 @default.
• W2080740075 cites W2002218208 @default.
• W2080740075 cites W2004189982 @default.
• W2080740075 cites W2016431095 @default.
• W2080740075 cites W2017082514 @default.
• W2080740075 cites W2023716263 @default.
• W2080740075 cites W2030437539 @default.
• W2080740075 cites W2033684964 @default.
• W2080740075 cites W2036782924 @default.
• W2080740075 cites W2043153233 @default.
• W2080740075 cites W2043530474 @default.
• W2080740075 cites W2050247320 @default.
• W2080740075 cites W2052457351 @default.
• W2080740075 cites W2056064465 @default.
• W2080740075 cites W2065973818 @default.
• W2080740075 cites W2068754874 @default.
• W2080740075 cites W2071984901 @default.
• W2080740075 cites W2075045956 @default.
• W2080740075 cites W2077208233 @default.
• W2080740075 cites W2078665311 @default.
• W2080740075 cites W2082127094 @default.
• W2080740075 cites W2087514259 @default.
• W2080740075 cites W2093071967 @default.
• W2080740075 cites W2094970470 @default.
• W2080740075 cites W2101491014 @default.
• W2080740075 cites W2122619564 @default.
• W2080740075 cites W2146303074 @default.
• W2080740075 cites W2147888991 @default.
• W2080740075 cites W2168662301 @default.
• W2080740075 cites W4232409431 @default.
• W2080740075 doi "https://doi.org/10.1063/1.455380" @default.
• W2080740075 hasPublicationYear "1988" @default.
• W2080740075 type Work @default.
• W2080740075 sameAs 2080740075 @default.
• W2080740075 citedByCount "82" @default.
• W2080740075 countsByYear W20807400752015 @default.
• W2080740075 countsByYear W20807400752016 @default.
• W2080740075 countsByYear W20807400752020 @default.
• W2080740075 countsByYear W20807400752021 @default.
• W2080740075 crossrefType "journal-article" @default.
• W2080740075 hasAuthorship W2080740075A5004149083 @default.
• W2080740075 hasAuthorship W2080740075A5028330542 @default.
• W2080740075 hasAuthorship W2080740075A5037746247 @default.
• W2080740075 hasAuthorship W2080740075A5069188516 @default.
• W2080740075 hasAuthorship W2080740075A5075279360 @default.
• W2080740075 hasAuthorship W2080740075A5076662158 @default.
• W2080740075 hasBestOaLocation W20807400752 @default.
• W2080740075 hasConcept C121332964 @default.
• W2080740075 hasConcept C131538251 @default.
• W2080740075 hasConcept C178790620 @default.
• W2080740075 hasConcept C184779094 @default.
• W2080740075 hasConcept C185592680 @default.
• W2080740075 hasConcept C31100168 @default.
• W2080740075 hasConcept C32909587 @default.
• W2080740075 hasConcept C39984356 @default.
• W2080740075 hasConcept C41999313 @default.
• W2080740075 hasConcept C69523127 @default.
• W2080740075 hasConceptScore W2080740075C121332964 @default.
• W2080740075 hasConceptScore W2080740075C131538251 @default.
• W2080740075 hasConceptScore W2080740075C178790620 @default.
• W2080740075 hasConceptScore W2080740075C184779094 @default.
• W2080740075 hasConceptScore W2080740075C185592680 @default.
• W2080740075 hasConceptScore W2080740075C31100168 @default.
• W2080740075 hasConceptScore W2080740075C32909587 @default.
• W2080740075 hasConceptScore W2080740075C39984356 @default.
• W2080740075 hasConceptScore W2080740075C41999313 @default.
• W2080740075 hasConceptScore W2080740075C69523127 @default.
• W2080740075 hasIssue "11" @default.
• W2080740075 hasLocation W20807400751 @default.
• W2080740075 hasLocation W20807400752 @default.
• W2080740075 hasOpenAccess W2080740075 @default.
• W2080740075 hasPrimaryLocation W20807400751 @default.
• W2080740075 hasRelatedWork W1976055495 @default.
• W2080740075 hasRelatedWork W1986505327 @default.
• W2080740075 hasRelatedWork W2029649045 @default.
• W2080740075 hasRelatedWork W2053735213 @default.
• W2080740075 hasRelatedWork W2062752848 @default.
• W2080740075 hasRelatedWork W2078093079 @default.
• W2080740075 hasRelatedWork W2153997897 @default.
• W2080740075 hasRelatedWork W2499280553 @default.

• next