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• W2080752574 abstract "Abstract The structures of the N , N ′-dimethylpropyleneurea (DMPU) solvated zinc(II) and cadmium(II) ions have been studied in solution by extended X-ray absorption fine structure (EXAFS) and large angle X-ray scattering (LAXS), and in solid state as the trifluoromethanesulfonate salts by EXAFS and crystallography. The DMPU solvated zinc(II) ion is four-coordinated in a tetrahedral fashion with a mean Zn–O bond distance of 1.925(6) A in solid state, while the mean Zn–O bond distance is much longer in solution, 1.99(2) A, suggesting that a five-coordinated solvate complex is dominating. As this Zn–O bond distance is somewhat shorter than expected for a five-coordinated zinc(II) complex the presence of a transient four-coordinated solvate complex in small amounts is possible. The DMPU solvated cadmium(II) ion is six-coordinated in an octahedral fashion in the solid state with a mean Cd–O bond distance of 2.260(9) A. The crystal structure displays severe disorder of both the hexakis( N , N ′-dimethylpropyleneurea)cadmium and trifluoromethanesulfonate ions. In this case, the mean Cd–O bond distance is slightly shorter in solution, 2.24(1) A, which may indicate the existence of a transient dissociative five-coordinated species." @default.
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• W2080752574 date "2007-03-01" @default.
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• W2080752574 title "A structural study of the N,N′-dimethylpropyleneurea solvated zinc(II) and cadmium(II) ions in solution and crystalline state" @default.
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• W2080752574 doi "https://doi.org/10.1016/j.molliq.2006.08.059" @default.
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