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- W2080758675 abstract "The efficiency of glycosylation of glycosyl acceptors supported on a hyperbranched polyester (Boltorn H-50) by an activated trichloroacetamidate donor was investigated as a function of the polymer loading. Loading of the hyperbranched polyester with an o-nitrobenzyl photolabile linker at 25% loading capacity (corresponding to 1.36 mmol/g) and using five equivalents of the glycosyl donor was optimal for quantitative transformation (>98%) at both the mono- and disaccharide stage. The disaccharide product obtained under these optimized conditions was isolated in 16% yield over five steps." @default.
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- W2080758675 date "2005-06-07" @default.
- W2080758675 modified "2023-09-26" @default.
- W2080758675 title "Hyperbranched Polyester Supported Disaccharide Synthesis: The Effect of Loading Level on Glycosylation Efficiency" @default.
- W2080758675 doi "https://doi.org/10.1055/s-2005-869863" @default.
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