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• W2080768346 abstract "The anion exchange polyphenylene membrane containing imidazolium hydroxide ionic functional group was synthesized by sequential chloromethylation, substitution with 1-methylimidazole and ion exchange. The imidazolium hydroxide Parmax 1200 membrane has all carbon-carbon bonds without ether linkages, which would be chemically strong. The polyphenylene structure of Parmax provides a stiff and resistant backbone, whereas the pendant benzoyl group provides sites for chemical modifications. The resulting ionomer membrane showed ion exchange capacity (IEC) of 2.14 mmol g <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>-1</sup> with maximum chloromethylation yield. The imidazolium-functionalized copolymer membrane showed lower water affinity and high durability in alkaline condition. It exhibited hydroxide ion conductivity above 10 <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>-2</sup> S cm <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>-1</sup> at room temperature and good chemical stability for up to seven days without significant losses of ion conductivity. The structural properties of the synthesized polymer membrane were investigated by <sup xmlns:mml=http://www.w3.org/1998/Math/MathML xmlns:xlink=http://www.w3.org/1999/xlink>1</sup> H NMR spectroscopy and FT-IR. The membranes were studied by IEC, water uptake, and conductivity assessment." @default.
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• W2080768346 date "2014-03-01" @default.
• W2080768346 modified "2023-09-26" @default.
• W2080768346 title "Anion conductive imidazolium-based Parmax alkaline membrane for fuel cell applications" @default.
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• W2080768346 doi "https://doi.org/10.1109/irec.2014.6827011" @default.
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