Matches in SemOpenAlex for { <https://semopenalex.org/work/W2080771839> ?p ?o ?g. }
Showing items 1 to 73 of
73
with 100 items per page.
- W2080771839 endingPage "229" @default.
- W2080771839 startingPage "223" @default.
- W2080771839 abstract "Steroids. 67. 16,17-Aziridines of 3-Methoxy-estra-1,3,5(10)-triene Reduction of the 16β-azido-17-α-mesyloxy- and 16α-azido-17β-mesyloxy-estra-1,3,5(10)-triene-3-methylether (2 and 10) with hydrazine hydrate and Raney nickel gives the 16,17-trans-aminoalcohol-O-mesylates 3 and 11. Treatment of 3 with basic reagents affords products of Wagner-Meerwein rearrangement, 11 gives under analogous conditions the 16α-amino-17β-hydroxy compound and the 16α, 17α-aziridine. Smooth ring closure to the 16,17-N-mesylaziridines 6 and 13 can be achieved by reaction of the 16,17-trans-mesylamido-mesyloxy compounds 8 and 12 with bases in DMSO. The torsional angles of the reactive groups are discussed." @default.
- W2080771839 created "2016-06-24" @default.
- W2080771839 creator A5063783181 @default.
- W2080771839 creator A5076214953 @default.
- W2080771839 date "1981-01-01" @default.
- W2080771839 modified "2023-09-25" @default.
- W2080771839 title "Steroide. 67. 16,17-Aziridine des Östra-1,3,5(10)-trien-3-methylethers" @default.
- W2080771839 cites W1967876433 @default.
- W2080771839 cites W1996036288 @default.
- W2080771839 cites W2006972495 @default.
- W2080771839 cites W2009878502 @default.
- W2080771839 cites W2014433215 @default.
- W2080771839 cites W2047215371 @default.
- W2080771839 cites W2078394348 @default.
- W2080771839 cites W2089519936 @default.
- W2080771839 cites W2103367808 @default.
- W2080771839 cites W2105296619 @default.
- W2080771839 cites W2166100639 @default.
- W2080771839 cites W1525697362 @default.
- W2080771839 cites W1966921527 @default.
- W2080771839 doi "https://doi.org/10.1002/prac.19813230206" @default.
- W2080771839 hasPublicationYear "1981" @default.
- W2080771839 type Work @default.
- W2080771839 sameAs 2080771839 @default.
- W2080771839 citedByCount "1" @default.
- W2080771839 crossrefType "journal-article" @default.
- W2080771839 hasAuthorship W2080771839A5063783181 @default.
- W2080771839 hasAuthorship W2080771839A5076214953 @default.
- W2080771839 hasConcept C155647269 @default.
- W2080771839 hasConcept C161790260 @default.
- W2080771839 hasConcept C178790620 @default.
- W2080771839 hasConcept C185592680 @default.
- W2080771839 hasConcept C2776419971 @default.
- W2080771839 hasConcept C2776597398 @default.
- W2080771839 hasConcept C2778544067 @default.
- W2080771839 hasConcept C2780378348 @default.
- W2080771839 hasConcept C2781060337 @default.
- W2080771839 hasConcept C40875361 @default.
- W2080771839 hasConcept C43617362 @default.
- W2080771839 hasConcept C71240020 @default.
- W2080771839 hasConceptScore W2080771839C155647269 @default.
- W2080771839 hasConceptScore W2080771839C161790260 @default.
- W2080771839 hasConceptScore W2080771839C178790620 @default.
- W2080771839 hasConceptScore W2080771839C185592680 @default.
- W2080771839 hasConceptScore W2080771839C2776419971 @default.
- W2080771839 hasConceptScore W2080771839C2776597398 @default.
- W2080771839 hasConceptScore W2080771839C2778544067 @default.
- W2080771839 hasConceptScore W2080771839C2780378348 @default.
- W2080771839 hasConceptScore W2080771839C2781060337 @default.
- W2080771839 hasConceptScore W2080771839C40875361 @default.
- W2080771839 hasConceptScore W2080771839C43617362 @default.
- W2080771839 hasConceptScore W2080771839C71240020 @default.
- W2080771839 hasIssue "2" @default.
- W2080771839 hasLocation W20807718391 @default.
- W2080771839 hasOpenAccess W2080771839 @default.
- W2080771839 hasPrimaryLocation W20807718391 @default.
- W2080771839 hasRelatedWork W2003688997 @default.
- W2080771839 hasRelatedWork W2031901636 @default.
- W2080771839 hasRelatedWork W2062794911 @default.
- W2080771839 hasRelatedWork W2078129765 @default.
- W2080771839 hasRelatedWork W2104853035 @default.
- W2080771839 hasRelatedWork W2225633998 @default.
- W2080771839 hasRelatedWork W2339182987 @default.
- W2080771839 hasRelatedWork W2398307502 @default.
- W2080771839 hasRelatedWork W2950046175 @default.
- W2080771839 hasRelatedWork W2950643693 @default.
- W2080771839 hasVolume "323" @default.
- W2080771839 isParatext "false" @default.
- W2080771839 isRetracted "false" @default.
- W2080771839 magId "2080771839" @default.
- W2080771839 workType "article" @default.