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- W2080784618 abstract "Excess molar volumes VmE of “(triethylamine or acetone or diethylether) + trichloromethane’ and of “(triethylamine or diethylamine) + methanol’ were measured at 298.15 K as a function of mole fraction x and pressure p between 10 MPa and a maximum pressure of 200 MPa; (triethylamine + trichloromethane) was also studied at 308.15 K. The VmE values were determined dilatometrically as the change of volume on mixing the pure components under pressure in a special high-pressure mixing cell mounted in an autoclave. For (acetone + trichloromethane) S-shaped VmE(x) curves at given T and p were found whereas all other mixtures exhibited negative values, that decrease in absolute value with increasing pressure, over the whole mole-fraction range. For the correlation of the VmE(p) curves for given T and p a Simon-type equation was used and the VmE(x) curves were fitted to an equation. From the VmEs obtained, the changes ΔGmE of the excess molar Gibbs energy with pressure were calculated, e.g. GmE decreases by about 310 J·mol−1 between 0.1 and 200 MPa for “0.5(C2H5)3N + 0.5CH3OH’." @default.
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- W2080784618 date "1982-08-01" @default.
- W2080784618 modified "2023-10-18" @default.
- W2080784618 title "Excess volumes of (ethanol+methylcyclopentane) from 10 to 200 MPa at 298.15 and 323.15 K" @default.
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- W2080784618 doi "https://doi.org/10.1016/0021-9614(82)90179-3" @default.
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