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- W2080784641 abstract "We investigate the Stark effect for spectral transitions between low-lying levels of atoms and ions. We find that often a strong cancellation of the shifts of the lower and upper levels occurs, resulting in a significant reduction in the shift. For accurate calculations, therefore, one has to account for the influence of high-principal-quantum-number and continuum levels. As examples, the shifts, splitting, and intensities of the components of the Li I $2s$-$2p$, Na I $3s$-$3p$, Ba II $5d$-$6p$, Ba II $6s$-$6p$, and the quadrupole Ba II $6s$-$5d$ (shifts only) transitions are calculated for electric fields up to $ensuremath{approx}$20 MV/cm. Comparison of the calculated shift parameters to experimental data for the Li I $2s$-$2p$, Na I $3s$-$3p$, and Ba II $6s$-$5d$ lines, available as yet only for low fields for which the effect is quadratic, showed an excellent agreement for most of these lines." @default.
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- W2080784641 date "1997-10-01" @default.
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- W2080784641 title "Effect of high-<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mi>n</mml:mi></mml:math>and continuum eigenstates on the Stark effect of resonance lines of atoms and ions" @default.
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- W2080784641 doi "https://doi.org/10.1103/physreva.56.2713" @default.
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