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- W2080789944 abstract "Two new strontium-rich manganites with a layered structure, Bi0.4Sr2.6MnO5−δ and Bi0.9Sr3.1MnO6−δ, have been synthesized and characterized, using X-ray powder diffraction and electron microscopy. The first, Bi0.4Sr2.6MnO5−δ, crystallizes in the space group I4/mmm with a=5.3756(1) Å and c=35.578(1) Å and shows for the first time the possibility to stabilize a manganite with a 1201-type structure. The second, Bi0.9Sr3.1MnO6−δ, which crystallizes in the P21 space group with a=5.2829(2) Å, b=5.2998(2) Å, c=23.9906(6) Å, and γ=90.27(2)°, exhibits a 2201 unmodulated structure. Both oxides are characterized by a 1:1 ordering between bismuth and strontium forming rows parallel to b→, while a quadrupling of the c parameter is observed in the case of the 1201 structure. The investigation of their magnetic properties shows a complex magnetic behavior connected to the existence of trivalent manganese in MnO2 planes." @default.
- W2080789944 created "2016-06-24" @default.
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- W2080789944 date "2000-05-01" @default.
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- W2080789944 title "Two New Sr-Rich Layered Manganites with a 1:1 Bi–Sr Ordering: 1201 Bi0.4Sr2.6MnO5−δ and 2201 Bi0.9Sr3.1MnO6−δ" @default.
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- W2080789944 doi "https://doi.org/10.1006/jssc.2000.8641" @default.
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