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- W2080792130 abstract "As-synthesized zeolite β has been successfully used as a template for the preparation, via chemical vapor deposition, of well ordered zeolite-like carbon materials. The carbon materials have high surface area (1720−2535 m2/g) and high pore volume (1.09−1.56 cm3 g-1) and exhibit some zeolite-like structural ordering replicated from the zeolite template. Carbon materials prepared at 800 and 850 °C are nongraphitic and retain the particle morphology of the zeolite templates. Carbon prepared at 900 °C contains some graphitic domains (as indicated by XRD patterns) and irregular particles that are dissimilar to the zeolite template particles. We observed hydrogen uptake of up to 5.3 wt % at −196 °C and 20 bar, and 2.3 wt % at 1 bar, for the carbon materials. The hydrogen uptake is dependent on the surface area of the carbons. The use of as-synthesized (rather than calcined) zeolite β significantly improves the carbon yield and reduces the number of steps in the preparation of the templated carbons." @default.
- W2080792130 created "2016-06-24" @default.
- W2080792130 creator A5007033958 @default.
- W2080792130 creator A5086847641 @default.
- W2080792130 date "2008-01-31" @default.
- W2080792130 modified "2023-09-26" @default.
- W2080792130 title "Synthesis and High Hydrogen Storage Capacity of Zeolite-Like Carbons Nanocast Using As-Synthesized Zeolite Templates" @default.
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- W2080792130 doi "https://doi.org/10.1021/jp076603f" @default.
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