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- W2080793480 abstract "The cleavage rates of transient aromatic radical anions of halobenzoic acids (kc=103–109 s−1) have been measured in water using a photoelectrochemical method based on photoelectron injection from a metal into an electrolyte solution. Values of kc have been determined from the dependence of the photoinduced cathode charge on the concentration of substances studied. Results indicate that kc depends on the nature of the halogen and its position in the ring relative to the carboxylate group, increasing in the series F<Cl<Br and meta<para<ortho (Cl, Br) and meta<ortho<para (F). The structure of the transient state and the factors determining the cleavage rates of the radical anions are discussed." @default.
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- W2080793480 date "1989-05-01" @default.
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- W2080793480 title "Photoelectrochemical study of the radical anion cleavage rates in aromatic molecules: Halobenzoic acids" @default.
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- W2080793480 doi "https://doi.org/10.1016/0009-2614(89)87244-6" @default.
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