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• W2080794238 abstract "Catalytic conversion of HMF to valuable chemicals was achieved over a Cu-doped porous metal oxide in supercritical methanol. The hydrotalcite catalyst precursor is prepared following simple synthetic procedures, using inexpensive and earth-abundant starting materials in aqueous solutions. The hydrogen equivalents needed for the reductive deoxygenation of HMF originate from the solvent itself upon its reforming. Dimethylfuran, dimethyltetrahydrofuran and 2-hexanol were obtained in good yields. At milder reaction temperatures, a combined yield (DMF + DMTHF) of 58% was achieved. Notably, the formation of higher boiling side products and undesired char from HMF is not detected under these reaction conditions." @default.
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• W2080794238 date "2012-01-01" @default.
• W2080794238 modified "2023-10-02" @default.
• W2080794238 title "One-pot reduction of 5-hydroxymethylfurfural via hydrogen transfer from supercritical methanol" @default.
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• W2080794238 doi "https://doi.org/10.1039/c2gc35667h" @default.
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