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- W2080796398 abstract "Phase stability of CeVO4 under pressure has been investigated using synchrotron based angle dispersive x-ray diffraction (ADXRD), electrical resistance and first principles calculations. The results indicate that the ambient zircon structure of the compound transforms to a low symmetry monoclinic monazite phase beyond 3.8 GPa with nearly 8.6% volume discontinuity. Beyond 11 GPa, the pattern could be fitted to a similar monazite structure which is about 12.7% denser and has a much larger monoclinic beta angle. On pressure release the first monoclinic phase is recovered. The electrical resistance data show a large drop in resistance with pressure indicating substantial narrowing down of the band gap. Electronic structure calculations support these observations and suggest possible pressure induced metallization in this material." @default.
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- W2080796398 date "2013-07-01" @default.
- W2080796398 modified "2023-09-23" @default.
- W2080796398 title "Phase transition and possible metallization in CeVO4 under pressure" @default.
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- W2080796398 doi "https://doi.org/10.1016/j.jssc.2013.04.036" @default.
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